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11.
Sulfate and selenate adsorption on iron oxides are important reactions in natural systems under a very wide range of pH values, ionic strengths, and electrolyte compositions. Under such conditions, spectroscopic and theoretical calculations have demonstrated the potential importance of a variety of surface species. Understanding the variations in the surface speciation of these oxyanions is fundamental to prediction of their partitioning between minerals and aqueous solutions. In the present study, published experimental spectroscopic and theoretical molecular evidence of the identity of sulfate/selenate surface species are integrated with a surface complexation model consistent with a wide variety of experimental adsorption, surface titration, and proton coadsorption data to define the surface speciation of sulfate and selenate on iron oxides under a wide range of conditions. The analysis was carried out with the extended triple layer model (ETLM) taking into account the electrostatics of water dipole desorption during ligand exchange reactions. On seven out of eight goethites studied, sulfate and selenate surface reactions can be represented by the formation of a monodentate-mononuclear inner-sphere and a bidentate-binuclear outer-sphere (or H-bonded) species according to
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12.
Planetary, stellar and galactic physics often rely on the general restricted gravitational $N$ -body problem to model the motion of a small-mass object under the influence of much more massive objects. Here, I formulate the general restricted problem entirely and specifically in terms of the commonly used orbital elements of semimajor axis, eccentricity, inclination, longitude of ascending node, argument of pericentre, and true anomaly, without any assumptions about their magnitudes. I derive the equations of motion in the general, unaveraged case, as well as specific cases, with respect to both a bodycentric and barycentric origin. I then reduce the equations to three-body systems, and present compact singly- and doubly-averaged expressions which can be readily applied to systems of interest. This method recovers classic Lidov–Kozai and Laplace–Lagrange theory in the test particle limit to any order, but with fewer assumptions, and reveals a complete analytic solution for the averaged planetary pericentre precession in coplanar circular circumbinary systems to at least the first three nonzero orders in semimajor axis ratio. Finally, I show how the unaveraged equations may be used to express resonant angle evolution in an explicit manner that is not subject to expansions of eccentricity and inclination about small nor any other values.  相似文献   
13.
The Northern Humboldt Current Ecosystem is one of the most productive in the world in terms of fish production. Its location near to the equator permits strong upwelling under relatively low winds, thus creating optimal conditions for the development of plankton communities. These communities ultimately support abundant populations of grazing fish such as the Peruvian anchoveta, Engraulis ringens. The ecosystem is also subject to strong inter-annual environmental variability associated with the El Niño Southern Oscillation (ENSO), which has major effects on nutrient structure, primary production, and higher trophic levels. Here our objective is to model the contributions of several external drivers (i.e. reconstructed phytoplankton changes, fish immigration, and fishing rate) and internal control mechanisms (i.e. predator-prey) to ecosystem dynamics over an ENSO cycle. Steady-state models and time-series data from the Instituto del Mar del Perú (IMARPE) from 1995 to 2004 provide the base data for simulations conducted with the program Ecopath with Ecosim. In simulations all three external drivers contribute to ecosystem dynamics. Changes in phytoplankton quantity and composition (i.e. contribution of diatoms and dino- and silicoflagellates), as affected by upwelling intensity, were important in dynamics of the El Niño of 1997–98 and the subsequent 3 years. The expansion and immigration of mesopelagic fish populations during El Niño was important for dynamics in following years. Fishing rate changes were the most important of the three external drivers tested, helping to explain observed dynamics throughout the modeled period, and particularly during the post-El Niño period. Internal control settings show a mix of predator–prey control settings; however a “wasp-waist” control of the ecosystem by small pelagic fish is not supported.  相似文献   
14.
We have performed 2D bulge/bar/disc decompositions using g , r and i -band images of a representative sample of nearly 1000 galaxies from the Sloan Digital Sky Survey. We show that the Petrosian concentration index is a better proxy for the bulge-to-total ratio than the global Sérsic index. We show that pseudo-bulges can be distinguished from classical bulges as outliers in the Kormendy relation. We provide the structural parameters and distributions of stellar masses of ellipticals, classical bulges, pseudo-bulges, discs and bars, and find that 32 per cent of the total stellar mass in massive galaxies in the local universe is contained in ellipticals, 36 per cent in discs, 25 per cent in classical bulges, 3 per cent in pseudo-bulges and 4 per cent in bars. Pseudo-bulges are currently undergoing intense star formation activity and populate the blue cloud of the colour–magnitude diagram. Most (though not all) classical bulges are quiescent and populate the red sequence of the diagram. Classical bulges follow a correlation between the bulge Sérsic index and bulge-to-total ratio, while pseudo-bulges do not. In addition, for a fixed bulge-to-total ratio, pseudo-bulges are less concentrated than classical bulges. Pseudo-bulges follow a mass–size relation similar to that followed by bars, and different from that followed by classical bulges. In the fundamental plane, pseudo-bulges occupy the same locus as discs. While these results point out different formation processes for classical and pseudo-bulges, we also find a significant overlap in their properties, indicating that the different processes might happen concomitantly. Finally, classical bulges and ellipticals follow offset mass–size relations, suggesting that high-mass bulges might not be simply high-mass ellipticals surrounded by discs.  相似文献   
15.
Abstract

This article presents a comparison between real-time discharges calculated by a flash-flood warning system and post-event flood peak estimates. The studied event occurred on 15 and 16 June 2010 at the Argens catchment located in the south of France. Real-time flood warnings were provided by the AIGA (Adaptation d’Information Géographique pour l’Alerte en Crue) warning system, which is based on a simple distributed hydrological model run at a 1-km2 resolution using radar rainfall information. The timing of the warnings (updated every 15 min) was compared to the observed flood impacts. Furthermore, “consolidated” flood peaks estimated by an intensive post-event survey were used to evaluate the AIGA-estimated peak discharges. The results indicated that the AIGA warnings clearly identified the most affected areas. However, the effective lead-time of the event detection was short, especially for fast-response catchments, because the current method does not take into account any rainfall forecast. The flood peak analysis showed a relatively good correspondence between AIGA- and field-estimated peak values, although some differences were due to the rainfall underestimation by the radar and rainfall–runoff model limitations.
Editor Z.W. Kundzewicz; Guest editor R.J. Moore

Citation Javelle, P., Demargne, J., Defrance, D., Pansu, J. and Arnaud, P., 2014. Evaluating flash-flood warnings at ungauged locations using post-event surveys: a case study with the AIGA warning system. Hydrological Sciences Journal, 59 (7), 1390–1402. http://dx.doi.org/10.1080/02626667.2014.923970  相似文献   
16.
The effect of different structures configurations on the collision between adjacent planar RC building frames subjected to strong earthquakes is examined in this paper. Two 5‐storey and two 8‐storey frames, regular or with setbacks, are combined together to produce nine different pairs of adjacent RC structures. These pairs of buildings are subjected to six strong ground motions that are absolutely compatible with the design process. Various parameters are investigated such as maximum displacements, permanent displacements, members' ductility and internal forces and interstorey drift ratios. It is concluded that the effect of collision of adjacent frames seems to be unfavourable for most of the cases and, therefore, the structural pounding phenomenon is rather detrimental than beneficial. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
17.
Microstructure and hydraulic conductivity of a compacted lime-treated soil   总被引:1,自引:0,他引:1  
Under a given compaction energy and procedure, it is known that maximum dry density of a soil is lowered due to lime addition. This modification of maximum dry density could alter the hydraulic conductivity of the soil. The main object of this study was to assess the impact of lime-stabilization on a silt soil microstructure and then on saturated hydraulic conductivity. An investigation at the microscopic level with mercury intrusion porosimetry showed that lime treatment induced the formation of a new small class, with a diameter lower than 3 × 103 Å in the compacted soil. This class is responsible for the difference in dry density between the treated and the untreated sample after compaction. It is shown that this small pores class was not altered by the compaction water content, the compaction procedure or the dry density. As in untreated soils, only the larger pores were modified by the compaction water content and the compaction procedure in the lime treated samples. The hydraulic conductivity appeared to be only related to the largest pores volume of the tested silt, regardless of lime treatment. Therefore, this study demonstrated that even if addition of lime resulted in a dramatic change of the maximum dry density of the tested silty soil, its effect on hydraulic conductivity is limited.  相似文献   
18.
An interdisciplinary study of a small sedimentary basin at Neumark Nord 2 (NN2), Germany, has yielded a high-resolution record of the palaeomagnetic Blake Event, which we are able to place at the early part of the last interglacial pollen sequence documented from the same section. We use this data to calculate the duration of this stratigraphically important event at 3400 ± 350 yr. More importantly, the Neumark Nord 2 data enables precise terrestrial-marine correlation for the Eemian stage in central Europe. This shows a remarkably large time lag of ca. 5000 yr between the MIS 5e ‘peak’ in the marine record and the start of the last interglacial in this region.  相似文献   
19.
Understanding the biogeochemical process of Hg is critical in the overall evaluation of the ecological impacts resulting from the reuse of Hg-contaminated dredged sediment. Sediment banks (V1 and V2) were constructed with freshly dredged sediments from a navigational channel in Venice Lagoon, Italy, with the goal of clarifying potential differences in the biogeochemistry of Hg between the reused dredged sediments and those from surrounding sites (SS1 and S2). Toward this purpose, Hg and monomethylmercury (MMHg) concentrations, and Hg methylation rates (MMRs) in the surface 2.5 cm sediments were monitored, along with ammonium, iron, sulfate and sulfide concentrations in the pore waters of banks and surrounding sites from November 2005 to February 2007. Pore water analyses indicate that the bank sediments are characterized by lower levels of sulfate and iron, and by higher levels of ammonium and sulfide compared to the surrounding sediments. With respect to Hg speciation, the fractions of MMHg in total Hg (%MMHg/Hg) and the MMRs were significantly lower in the bank V1 compared to those in the reference site SS1, whereas the %MMHg/Hg and the MMRs were similar between V2 and S2. A negative correlation is found between the logarithm of the particle-water partition coefficient of Hg and the MMR, indicating that the reduced MMRs in V1 are caused by the limited concentrations of dissolved Hg. Organic matter appears to play a key role in the control of MMR via the control of Hg solubility.  相似文献   
20.
The increasing number and variety of extrasolar planets illustrates the importance of characterizing planetary perturbations. Planetary orbits are typically described by physically intuitive orbital elements. Here, we explicitly express the equations of motion of the unaveraged perturbed two-body problem in terms of planetary orbital elements by using a generalized form of Gauss’ equations. We consider a varied set of position and velocity-dependent perturbations, and also derive relevant specific cases of the equations: when they are averaged over fast variables (the “adiabatic” approximation), and in the prograde and retrograde planar cases. In each instance, we delineate the properties of the equations. As brief demonstrations of potential applications, we consider the effect of Galactic tides. We measure the effect on the widest-known exoplanet orbit, Sedna-like objects, and distant scattered disk objects, particularly with regard to where the adiabatic approximation breaks down. The Mathematica code which can help derive the equations of motion for a user-defined perturbation is freely available upon request.  相似文献   
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